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Periodic table

From Academic Kids

The periodic table of the chemical elements, also called the Mendeleev periodic table, is a tabular display of the known chemical elements. First created by Dmitri Mendeleev, the elements are arranged by electron structure so that many chemical properties vary regularly across the table. Each element is listed by its atomic number and chemical symbol.

The standard table provides the necessary basics. There are also other methods for displaying the chemical elements for more details or different perspectives.

Contents

Groups

A group is a vertical column in the periodic table of the elements. There are 18 groups in the standard periodic table. Elements in a group have similar configurations of their valence shell electrons, which gives them similar properties.

Group numbers

There are three systems of group numbers; one using Arabic numerals, another using Roman numerals, and one using a combination of Roman numerals and Latin letters. The Roman numeral names are the original traditional names of the groups; the Arabic numeral names are a newer naming scheme recommended by the International Union of Pure and Applied Chemistry (IUPAC). The IUPAC scheme was developed to replace both older Roman numeral systems as they confusingly used the same names to mean different things.

Standard periodic table

Template:Periodic table

Other methods for displaying the chemical elements

And here is the periodic table (http://bic.beckman.uiuc.edu/mritab1/) for magnetic resonance.

Explanation of the structure of the periodic table

The number of electron shells an atom has determines to which period it belongs. Each shell is divided into different subshells, which as atomic number increases are filled in roughly this order:

1s
2s           2p
3s           3p
4s        3d 4p
5s        4d 5p
6s     4f 5d 6p
7s     5f 6d 7p
8s  5g 6f 7d 8p
...

Hence the structure of the table. Since the outermost electrons determine chemical properties, those tend to be similar within groups. Elements adjacent to one another within a group have similar physical properties, despite their significant differences in mass. Elements adjacent to one another within a period have similar mass but different properties.

For example, very near to nitrogen (N) in the second period of the chart are carbon (C) and oxygen (O). Despite their similarities in mass (they differ by only a few atomic mass units), they have extremely different properties, as can be seen by looking at their allotropes: diatomic oxygen is a gas that supports burning, diatomic nitrogen is a gas that does not support burning, and carbon is a solid which can be burned. (Yes, diamonds can be burned!)

In contrast, very near to chlorine (Cl) in the next-to-last group in the chart (the halogens) are fluorine (F) and bromine (Br). Despite their dramatic differences in mass, their allotropes have very similar properties. They are all highly corrosive (meaning they combine readily with metals to form metal halide salts); chlorine and fluorine are gases, while bromine is a very low-boiling liquid; chlorine and bromine are highly colored.

History

Main article: History of the periodic table

The original table was created without a knowledge of the inner structure of atoms: if one orders the elements by atomic mass, and then plots certain other properties against atomic mass, one sees an undulation or periodicity to these properties as a function of atomic mass. The first to recognize these regularities was the German chemist Johann Wolfgang D?einer who, in 1829, noticed a number of triads of similar elements:

Some triads
ElementAtomic massDensity
chlorine35.50.00156 g/cm3
bromine79.90.00312 g/cm3
iodine126.90.00495 g/cm3
 
calcium40.11.55 g/cm3
strontium87.62.6 g/cm3
barium1373.5 g/cm3

This was followed by the English chemist John Alexander Reina Newlands, who in 1865 noticed that the elements of similar type recurred at intervals of eight, which he likened to the octaves of music, though his law of octaves was ridiculed by his contemporaries. Finally, in 1869, the German Julius Lothar Meyer and the Russian chemist Dmitri Ivanovich Mendeleev almost simultaneously developed the first periodic table, arranging the elements by mass. However, Mendeleev plotted a few elements out of strict mass sequence in order to make a better match to the properties of their neighbours in the table, corrected mistakes in the values of several atomic masses, and predicted the existence and properties of a few new elements in the empty cells of his table. Mendeleev was later vindicated by the discovery of the electronic structure of the elements in the late 19th and early 20th century.

In the 1940s Glenn T. Seaborg identified the transuranic lathanides and the actinides, which may be placed within the table, or below (as shown above).


See also


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Chemistry

Analytical chemistry | Organic chemistry | Inorganic chemistry | Physical chemistry | Polymer chemistry | Biochemistry | Materials science | Environmental chemistry | Medicinal chemistry | Pharmacy | Thermochemistry | Electrochemistry | Nuclear chemistry | Computational chemistry | Photochemistry
Periodic table | List of inorganic compounds | List of organic compounds | List of biomolecules
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