Odd molecule

Odd molecule is a term invented by Gilbert N. Lewis in 1916 for a molecule containing an odd number of electrons. Such molecules, except those containing transition metals, are rare, usually colored and paramagnetic, that is, attracted by a magnet. Chlorine dioxide is an example, being a reddish-yellow gas. Nitrogen dioxide is another.

References

  • "The Atom and the Molecule", Gilbert N. Lewis, Journal of the American Chemical Society, volume 38 (1916), pages 762–786; received January 26, 1916.
  • "Classic Papers" - online copy of 1916 paper - 2005-V-17 (http://dbhs.wvusd.k12.ca.us/webdocs/Chem-History/Lewis-1916/Lewis-1916.html)
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