Spin glass
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A spin glass is a disordered material exhibiting high magnetic frustration. The origin of the behavior can be either a disordered structure (such as that of a conventional, chemical glass) or a disordered magnetic doping in an otherwise regular structure. Frustration refers to the inability of the system to remain in a single lowest energy state (the ground state). Spin glasses have many ground states which are never explored on experimental time scales.
It is the time dependence which distinguishes spin glasses from other magnetic systems. Beginning above the spin glass transition temperature, Tc, where the spin glass exhibits more typical magnetic behavior, (such as paramagnetism as discussed here but other kinds of magnetism are possible), if an external magnetic field is applied and the magnetization is plotted versus temperature, it follows the typical Curie law (in which magnetization is inversely proportional to temperature) until Tc is reached, at which point the magnetization becomes virtually constant (this value is called the field cooled magnetization). This is the onset of the spin glass phase. When the external field is removed, the spin glass has a rapid decrease of magnetization to a value called the remanent magnetization, and then a slow decay as the magnetization approaches zero (or some small fraction of the original value - this remains unknown). This decay is non-exponential and no single function can fit the curve of magnetization versus time adequately. This slow decay is particular to spin glasses. Experimental measurements on the order of days have shown continual changes above the noise level of instrumentation.
If a similar procedure was followed for a ferromagnetic substance, when the external field is removed, there would be a rapid change to a remanent value, but this value is a constant in time. For a paramagnet, when the external field is removed, the magnetization rapidly goes to zero. In each case, the change is very rapid and if carefully examined it is exponential decay with a very small time constant.
If instead, the spin glass is cooled below Tc in the absence of an external field, and then a field is applied, there is a rapid increase to a value called the zero-field-cooled magnetization, which is less than the field cooled magnetization, followed by a slow upward drift toward the field cooled value.
Surprisingly, the sum of the two complex functions of time (the zero-field-cooled and remanent magnetizations) is a constant, namely the field-cooled value, and thus both share identical functional forms with time (Nordblad et al.), at least in the limit of very small external fields.
In addition to unusual experimental properties, spin glasses are the subject of a great deal of theoretical and computational attention.
See also
- ferromagnetism
- antiferromagnetism
- phase
- phase transition
- ferromagnetic interaction
- antiferromagnetic interaction
- crystal structure
References
- J. A. Mydosh, Spin Glasses, Taylor & Francis (1995)
- P. Nordblad, L. Lundgren and L. Sandlund, J. Mag. and Mag. Mater. 54, pp. 185 (1986)ja:スピングラス