Copper

nickel – copper – zinc Cu Ag       Full table
General
Name, Symbol, Number	copper, Cu, 29
Chemical series	transition metals
Group, Period, Block	11 , 4, d
Density, Hardness	8920 kg/m3, 3.0
Appearance	copper, metallic
Atomic properties
Atomic weight	63.546 amu
Atomic radius (calc.)	135 (145) pm
Covalent radius	138 pm
van der Waals radius	140 pm
Electron configuration	[Ar]3d104s1
e- 's per energy level	2, 8, 18, 1
Oxidation states (Oxide)	2,1 (mildly basic)
Crystal structure	cubic, face-centered
Physical properties
State of matter	solid (diamagnetic)
Melting point	1357.6 K (1984.3 ?F)
Boiling point	2840 K (4653 ?F)
Molar volume	7.11 ×10-6 m3/mol
Heat of vaporization	300.3 kJ/mol
Heat of fusion	13.05 kJ/mol
Vapor pressure	0.0505 Pa at 1358 K
Speed of sound	3570 m/s at 293.15 K
Miscellaneous
Electronegativity	1.9 (Pauling scale)
Specific heat capacity	380 J/(kg·K)
Electrical conductivity	59.6 106/(m·Ω)
Thermal conductivity	401 W/(m·K)
1st ionization potential	745.5 kJ/mol
2nd ionization potential	1957.9 kJ/mol
3rd ionization potential	3555 kJ/mol
4th ionization potential	5536 kJ/mol
Most stable isotopes
iso NA half-life DM DE (MeV) DP 63Cu 69.17% Cu is stable with 34 neutrons 65Cu 30.83% Cu is stable with 36 neutrons
SI units & STP are used except where noted.

Copper is a chemical element in the periodic table that has the symbol Cu and atomic number 29.

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History

In Greek times, the metal was known by the name chalkos (χαλκός). In Roman times, it became known as aes Cyprium (aes being the generic Latin term for copper alloys such as bronze and other metals, and because so much of it was mined in Cyprus). From this, the phrase was simplified to cuprum and then eventually Anglicized into the English copper.

Copper was known to some of the oldest civilizations on record, and has a history of use that is at least 10,000 years old. A copper pendant was found in what is now northern Iraq that dates to 8700 BC. By 5000 BC there are signs of copper smelting, the refining of copper from simple copper oxides such as malachite or azurite. The earliest signs of gold use, by contrast, appear around 4000 BC.

There are copper and bronze artifacts from Sumerian cities that date to 3000 BC, and Egyptian artifacts in copper and copper alloyed with tin nearly as old. In one pyramid, a copper plumbing system was found that is 5000 years old.

The Egyptians found that adding a small amount of tin made the metal easier to cast, so bronze alloys are found in Egypt almost as soon as copper is found. Use of copper in ancient China dates to at least 2000 BC. By 1200 BC excellent bronzes were being made in China. Note that these dates are affected by wars and conquest, as copper is easily melted down and reused. In Europe, Oetzi the Iceman, a well preserved male dated to 3200 BC, was found with a copper tipped axe whose metal was 99.7% pure. High levels of arsenic in his hair suggests he was involved in copper smelting.

The use of bronze was so pervasive in a certain era of civilization that it has been named the Bronze Age. The transitional period in certain regions between the preceding Neolithic period and the Bronze Age is termed the Chalcolithic, with some high purity copper tools being used alongside stone tools.

Brass, an alloy of zinc and copper, was known to the Greeks but first used extensively by the Romans.

Copper was associated with the goddess Aphrodite/Venus in mythology and alchemy, owing to its lustrous beauty, its ancient use in producing mirrors, and its association with Cyprus, which was sacred to the goddess. In alchemy, the symbol for copper was also the symbol for the planet Venus.

Biological role

Copper is essential in all higher plants and animals. Copper is carried mostly in the bloodstream on a plasma protein called ceruloplasmin. When copper is first absorbed in the gut it is transported to the liver bound to albumin. Copper is found in a variety of enzymes, including the copper centers of cytochrome c oxidase, the Cu-Zn containing enzyme superoxide dismutase, and is the central metal in the oxygen carrying pigment hemocyanin. The blood of the horseshoe crab, Limulus polyphemus uses copper rather than iron for oxygen transport.

It is believed that zinc and copper compete for absorption in the digestive tract so that a diet that is excessive in one of these minerals may result in a deficiency in the other. The RDA for copper in normal healthy adults is 0.9 mg/day.

Toxicity

All copper compounds, unless otherwise known, should be treated as if they were toxic. 30g of copper sulfate is potentially lethal in humans. The suggested safe level of copper in drinking water for humans varies depending on the source, but tends to be pegged at 1.5 to 2 mg/L. The DRI Tolerable Upper Intake Level for adults of dietary copper from all sources is 10 mg/day.

An inherited condition called Wilson's disease causes the body to retain copper, since it is not excreted by the liver into the bile. This disease, if untreated, can lead to brain and liver damage. In addition, studies have found that people with mental illnesses such as schizophrenia had heightened levels of copper in their systems. However it is unknown at this stage whether the copper contributes to the mental illness, whether the body attempts to store more copper in response to the illness, or whether the high levels of copper are the result of the mental illness.

Miscellaneous hazards

The metal, when powdered, is a fire hazard. At concentrations higher than 1 mg/L, copper can stain clothes and items washed in water.

Physical characteristics

Copper is a reddish-coloured metal, with a high electrical and thermal conductivity (among pure metals at room temperature, only silver has a higher electrical conductivity). Copper may well be the oldest metal in use, as copper artifacts dating to 8700 BC have been found. Besides being part of various ores, copper can be found in the metallic form (i.e. native copper) in some locations.

There are two stable isotopes, ⁶³Cu and ⁶⁵Cu, along with a couple dozen radioisotopes. The vast majority of radioisotopes have half lives on the order of minutes or less, the longest lived, ⁶⁴Cu, has a half life of 12.7 hours, with two decay modes, leading to two separate products.

There are numerous alloys of copper - speculum metal is a copper/tin alloy, brass is a copper/zinc alloy, and bronze is a copper/tin alloy.

Compounds

Common oxidation states of copper include the less stable copper(I) state, Cu⁺¹; and the more stable copper(II) state, Cu⁺², which forms lovely blue or blue-green salts. Under unusual conditions, a +3 state can be obtained.

Copper(II) carbonate is green from which arises the unique appearance of copper-clad roofs or domes on some buildings. Copper(II) sulfate forms a blue crystalline pentahydrate which is perhaps the most familiar copper compound in the laboratory. It is used as a fungicide, known as Bordeau mixture.

There are two stable copper oxides, copper(II) oxide (CuO) and copper(I) oxide (Cu₂O). Copper oxides are used to make yttrium barium copper oxide (YBa₂Cu₃O_7-δ) or YBCO which forms the basis of many unconventional superconductors.

Other compounds : Copper(I) chloride, copper(II) chloride, copper(II) sulfide.

Occurrence

See Copper extraction for the main article.

Copper can be found as native copper in mineral form. Minerals such as the carbonates azurite (2CuCO₃Cu(OH)₂) and malachite (CuCO₃Cu(OH)₂) are sources of copper, as are sulfides such as chalcopyrite (CuFeS₂), bornite (Cu₅FeS₄), covellite (CuS), chalcocite (Cu₂S) and oxides like cuprite (Cu₂O).

Most copper extraction happens in large open pit mines in deposits that contain less than one percent copper. Examples include: Chuquicamata in Chile and El Chino mine in New Mexico.

The Intergovernmental Council of Copper Exporting Countries (CIPEC), defunct since 1992, once tried to play a similar role for copper as OPEC does for oil, but never achieved the same influence, not least because the second-largest producer, the United States, was never a member. Formed in 1967, its principal members were Chile, Peru, Zaire, and Zambia.

Applications

Copper is malleable and ductile, and is used extensively, in products such as:

• Copper wire.
• Copper plumbing.
• Doorknobs and other fixtures in houses.
• Statuary: The Statue of Liberty, for example, contains 179,200 pounds (81.3 Mg) of copper.
• Electromagnets.
• Motors, esp electromagnetic motors.
• Watt's steam engine.
• Electrical relays, electrical busbars and electrical switches.
• Vacuum tubes, cathode ray tubes, and the magnetrons in microwave ovens.
• Wave guides for microwave radiation.
• There is increasing use of copper in integrated circuits, replacing aluminium because of its superior conductivity.
• As a component of coins.
• In cookware, such as frying pans.
• Most flatware (knives, forks, spoons) contains some copper (nickel silver).
• Sterling silver, if it is to be used in dinnerware, must contain a few percent copper.
• As a component in ceramic glazes, and to color glass.
• Musical instruments, especially brass instruments.
• As a biostatic surface in hospitals, and to line parts of ships to protect against barnacles and mussels.
• Compounds, such as Fehling's solution, have applications in chemistry.
• Copper (II) sulfate is used as a poison and a water purifier.

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References

• Los Alamos National Laboratory - Copper (http://periodic.lanl.gov/elements/29.html)
• Copper: Technology & Competitiveness (Summary) Chapter 6: Copper Production Technology; Author: Office of Technology Assessment 2005